The 13 Best Shampoos for Hard Water of 2023

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Shampoo for Hard Water

Byrdie / Kevin Liang

Let’s start with the basics—what is hard water in the first place? It’s a term used to refer to water that’s full of minerals, which doesn’t necessarily sound like a bad thing, right? Here’s the issue: These minerals build up and harden on your hair, ultimately leaving it dry and brittle, not to mention causing color changes, too. Along with changes in your hair texture and tone, other tell-tale signs of hard water are a less-than-luscious lather with shampoo and soap, flat and easily-tangled hair, and a film-like layer on the skin.

Whether or not you have hard water ultimately comes down to where you live, but the good news is that there are ways to remedy the situation without packing up and moving. Installing a shower head filter and professional treatments are both options, but the easiest (and most cost-effective) fix is reaching for the right shampoo. A chelating formula attaches to the various minerals and metals found in hard water and whisks them away, while clarifying shampoos break down residue—whether from hard water or excess product—on the outer surface of the hair. Ingredients like vitamin C, apple cider vinegar, and EDTA are also ones to look for, as they can help remove mineral buildup.

Ready to add a clarifying shampoo to your shower routine? We tapped an expert for recommendations and even tried a few top-rated options ourselves to compile this list of shampoos for hard water that actually work. We considered shampoos (and shampoo-adjacent products) based on how well they clean hair, whether or not they clear scalp build up, and if they help hair feel its very best. We then cross-referenced our expert-recommended picks with the top-rated products we tried and landed on these best shampoos for hard water.

Best Overall

Malibu C Hard Water Wellness Shampoo

4.7
Malibu C Hard Water Wellness Shampoo

Courtesy of Amazon

What We Like
  • Strengthening, antioxidant-rich formula

  • Doesn't contain sulfates

What We Don't Like
  • Can stain white, gray, or super blonde hair

Mark DeBolt, celebrity colorist and co-founder of Mark Ryan Salon, counts this shampoo as the best product in the world for hair affected by hard water—and we’d have to agree. By simultaneously removing the waterborne minerals that damage and discolor your hair and depositing strengthening proteins and essential moisture, this formula takes a two-pronged approach to getting your hair into tip-top shape, making it the true standout of this list.

What’s more, the gentle, sulfate-free formula also contains antioxidants to protect hair from environmental damage such as UV rays, and pollutants. And while you can buy the sudser solo, there’s also a set that comes with an accompanying conditioner and more intense treatments. It’s also a favorite of Shelly Aguirre, a stylist at Maxine Salon in Chicago. She points out that she finds it works especially well for those who have chlorine build-up on their hair and says she loves the brand’s in-salon clarifying treatment as well.

We didn't experience any issues, but some reviewers online mention their white hair turning yellow after use. While the jury's still out on whether or not the shampoo or the hard water itself is to blame, it's something to keep in mind.

Price at time of publish: $38

Hair Type: Dry | Sulfate-Free: Yes | Scent: Orange sorbet blended with malibu fusion | Size: 33.8 fluid ounces | Cruelty-Free: Yes

Best Budget

GIRL+HAIR CLEAR+ Apple Cider Vinegar Clarifying Rinse

GIRL+HAIR CLEAR+ Apple Cider Vinegar Clarifying Rinse

 Amazon

What We Like
  • Suitable for many hair types

  • Tingly, cooling feel

What We Don't Like
  • Small bottle

When it comes to natural ingredients that can make a big impact on your hair, apple cider vinegar (aka ACV) reigns supreme. It’s a top pick for removing all kinds of build-up from your hair. Sure, you could go the DIY route and create your own vinegar rinse, but this wallet-friendly option is a much easier alternative. Use it in place of your regular shampoo a few times per week; organic apple cider vinegar gets rid of build-up from your hair and scalp without leaving either feeling dry or stripped.

Price at time of publish: $14

Hair Type: Chemically treated hair, wavy, curly, coiled, textured hair, relaxed hair | Sulfate-Free: Yes | Scent: Apple | Size: 10.1 fluid ounces | Cruelty-Free: Yes

Best Splurge

Oribe The Cleanse Clarifying Shampoo

ORIBE The Cleanse Clarifying Shampoo

Courtesy of Amazon

What We Like
  • Nourishing formula

  • Unique mousse consistency

  • Exfoliates scalp

What We Don't Like
  • Not the best smell

Some clarifying shampoos can have a bit of a clinical or medicinal feel to them, but that’s certainly not the case here. With a whipped, mousse-like texture and a sophisticated scent, this feels more like a fancy spa shampoo than a heavy-hitting hair purifier. Still, it does just that, using volcanic ash which, “polishes away dirt, oil, and product build-up,” says Aguirre of another one of her favorites. “Follow-up with a good conditioner and your hair will feel like new again,” she adds.

We don't mind it too much, but some may not like the scent. It's not loaded with added fragrances (which is a good thing), so it can smell somewhat scientific and kind of bland.

Price at time of publish: $49

Hair Type: Oily | Sulfate-Free: Yes | Scent: Cote d'Azur | Size: 7.1 fluid ounces | Cruelty-Free: Yes

Best Purifying

Ion Purifying Solutions Hard Water Shampoo

Ion Purifying Solutions Hard Water Shampoo

Amazon

What We Like
  • Affordable

  • Safe for daily use

What We Don’t Like
  • Doesn’t really have much of a scent

The name does say it all. Not only does this shampoo help to remove minerals (both from hard water and well water), it also helps prevent them from building up in the future. It adds shine and moisture, too, not to mention is safe for color-treated hair and is even gentle enough to use daily, not always the case for clarifying formulas. Happy reviewers also point out that they notice how much lighter and better their hair feels even after just one use. It doesn't have much of a scent, though, so those that prefer a potent smell might not be huge fans, but those with allergies to fragrance will especially like this one.

Price at time of publish: $19

Hair Type: All | Sulfate-Free: Yes | Scent: None | Size: 10.5 fluid ounces | Cruelty-Free: Yes

Best for Color-Treated Hair

Living Proof Perfect Hair Day Triple Detox Shampoo

4.8
Living Proof Perfect Hair Day Triple Detox Shampoo

Sephora

What We Like
  • Three sizes available

  • Good value

What We Don't Like
  • Can be a little drying

Generally speaking, any chelating or clarifying shampoo has the potential to strip color, but this pick is not only color-safe, but it also removes build-up from product, pollution, and hard water to keep your hue extra vibrant and shiny. Also cool: It comes with a hard water test strip, so you can see if you do have hard water. (Oh, and if you do—and have the time, of course—it’s best to leave this on for a minute or two before rinsing.)

Price at time of publish: $32

Hair Type: Chemically treated | Sulfate-Free: Yes | Scent: Citrus | Size: 5.4 fluid ounces | Cruelty-Free: Yes

Best for Itchy Scalps

Sachajuan Scalp Shampoo

Sachajuan Scalp Shampoo

Amazon

What We Like
  • Soothes scalp

  • Contains salicylic acid

  • Cooling sensation

What We Don't Like
  • Has sulfates

Along with causing hair issues, hard water can lead to a stressed-out scalp. More specifically, iron in the water can dry out the scalp and lead to flaking, explains Aguirre. Counteract it with this clarifying shampoo that deep cleans while also relieving dandruff and itchiness by balancing the pH of your scalp and using rosemary oil, ginger, and menthol to soothe irritation. This formula does contain sulfates, however we don't think it's the end of the world–if you're trying to avoid 'em, just skip this one.

Price at time of publish: $34

Hair Type: Balanced | Sulfate-Free: No | Scent: Rosemary | Size: 8.4 fluid ounces | Cruelty-Free: Yes

Best Detoxing

Ouai Detox Shampoo

4.2
Ouai Detox Shampoo

Sephora

What We Like
  • Combines chelating and clarifying benefits

  • Aesthetic-looking bottle

What We Don’t Like
  • Potent fragrance

This option feels completely spa-like and simple—but we promise it doesn't mess around. It foams nicely into a luscious lather and impresses with its hard-hitting clarifying duties. The formula contains chelating agents (that remove hard water deposits), apple cider vinegar (to gently remove build-up), plus hydrolyzed keratin (to soften your hair). FYI, for the best results, let it sit on your hair for 1 to 3 minutes before rinsing.

Price at time of publish: $30

Hair Type: All | Sulfate-Free: Yes | Scent: Ouai’s melrose place scent | Size: 10 fluid ounces | Cruelty-Free: Yes

Best for Curly Hair

Pattern Beauty Cleansing Shampoo

Pattern Beauty Clarifying Shampoo

Sephora

What We Like
  • Contains antioxidants

  • Doesn't strip hair

What We Don't Like
  • Can leave behind a filmy residue

As any curly girl will tell you, curly hair calls for a different product protocol than straight hair, and that is the case when it comes to removing build-up, too. This formula uses matcha green tea, aloe vera, and panthenol to get rid of residue, leaving your curls soft, smooth, and silky. Because it has such nourishing ingredients, some have noticed a filmy residue left behind after rinsing. Combat this by rinsing extra well and following up with another shampoo if need be.

Price at time of publish: $20

Hair Type: Low porosity | Sulfate-Free: Yes | Scent: Green tea | Size: 7.8 fluid ounces | Cruelty-Free: Yes

Best Pre-Shampoo

Color Wow Dream Filter Pre-Shampoo Mineral Remover

Color Wow Dream Filter Pre-Shampoo Mineral Remover

Courtesy of Amazon

What We Like
  • Easy to use

  • Great for swimmers

  • Helps preserve lighter blonde and gray

What We Don't Like
  • Extra step in haircare routine

While this technically may not be a shampoo, it most definitely earns a spot on this list thanks to its efficacy and how easy it is to use. Just spray it on all over your hair and leave it on for a minute or two before washing as normal; four different filters go to town removing even the slightest trace of damaging minerals. Still, it’s so gentle that you can even use it daily if needed, and while it works on all hair types and colors, it’s especially choice for lighter blonde or gray shades, which are more prone to mineral discoloration.

Price at time of publish: $24

Hair Type: All | Sulfate-Free: No | Scent: Fragrance-free | Size: 6.7 fluid ounces | Cruelty-Free: Yes

Best Scent

R+Co Oblivion Clarifying Shampoo

R+Co Oblivion Clarifying Shampoo

Courtesy of Amazon

What We Like
  • Effective formula

  • Fresh scent

  • Contains protein and amino acids

What We Don't Like
  • Smaller bottle

If you’re anything like us, a shampoo can be utterly amazing, but if it doesn’t smell good, you’re not going to use it. This smells clean, crisp, and fresh, exactly how we want our hair to smell. But it gets the cleansing job done, too, using rosemary leaf extract, tea tree oil, and witch hazel to break down gunk left behind from hard water, styling products, or both. If we could change one thing, it would be to make a bigger bottle available.

Hair Type: All | Sulfate-Free: Yes | Scent: Earthy | Size: 6 fluid ounces | Cruelty-Free: Yes

Best Micellar

Kristin Ess Scalp Purifying Micellar Shampoo

kristen ess

ULTA

What We Like
  • Gentle

  • Strengthening formula

What We Don't Like
  • Not super hydrating

Micellar waters are all the range in skincare—micelles are small molecules that act like magnets, attaching to and whisking away dirt, oil, and other grime. Here, they do just that, gently washing away impurities and keeping your scalp hydrated (because, FYI, healthy hair starts with a healthy scalp). The pointed tip makes it easy to deposit the shampoo directly onto your scalp, and we also love how nicely it lathers. Keep in mind that it's not super hydrating, so it's best to follow up with a creamy conditioner.

Price at time of publish: $15

Hair Type: All | Sulfate-Free: Yes | Scent: Fresh | Size: 10 fluid ounces | Cruelty-Free: Yes

Best Balancing

Briogeo Superfoods Mango + Cherry Balancing Shampoo

Briogeo Superfoods Mango + Cherry Balancing Shampoo

Dermstore

What We Like
  • Fruity scent

  • Rich in nutrients and antioxidants

What We Don't Like
  • Not great for those with a fragrance sensitivity

This juice-inspired formula from Briogeo is nutrient-rich and packed with vitamins and minerals to support healthy hair and scalp. Papaya enzyme, which is known to help balance oil production, takes center stage in addition to mango extract and cherry extract to help protect against free-radicals and promote overall hair health. You can expect your hair to feel and look healthy and strong (and smell incredibly fruity, too).

Price at time of publish: $30

Hair Type: All | Sulfate-Free: Yes | Scent: Fruity | Size: 12.5 fluid ounces | Cruelty-Free: Yes

Best Rinse

dpHUE Apple Cider Vinegar Hair Rinse

dphue ACV hair rinse
What We Like
  • Great for fine hair

What We Don't Like
  • Might not be intense enough for thick hair

ACV Hair Rinse is substitute for shampoo, ideally for those with fine hair. Aside from gently cleansing and removing impurities from the hair (without stripping hair color and essential natural oils), you can count on it to exfoliate the scalp and unclog hair follicles and help the scalp maintain an optimal pH balance.

Price at time of publish: $37

Hair Type: All | Sulfate-Free: Yes | Scent: Fruity | Size: 8.5 fluid ounces | Cruelty-Free: Yes

Final Verdict

When it comes to the best shampoos for combatting the effects of hard water on the hair, we’re giving top honors to the Malibu C Hard Water Wellness Shampoo. It takes a two-pronged approach to bring hair back to life: first, it removes the waterborne minerals that build up on the hair, and second, it deposits strengthening proteins and essential moisture. Plus, it protects against environmental stressors like UV rays and pollution. Hard water can also wreak havoc on the scalp, and the Sachajuan Scalp Shampoo does a stellar job at clarifying the hair while addressing issues like dandruff and itchiness. And for a budget-friendly option, the GIRL+HAIR CLEAR+ Apple Cider Vinegar Clarifying Rinse is a great option for removing all kinds of buildup from your hair and your scalp.

Meet the Expert

  • Mark DeBolt is a celebrity colorist and co-founder of Mark Ryan Salon. A protégé of celebrity colorist Marie Robinson, his areas of expertise include his signature blend of foil highlighting, balayage, and specialty color placement techniques. Currently, he’s an ambassador, educator, and hair color expert for Wella Professionals.
  • Shelly Aguirre is a stylist at Maxine Salon in Chicago. She specializes in precision cuts as well as extensions and is known for helping teach her clients about the best ways to embrace and style their hair texture.

What to Look For in a Shampoo for Hard Water

Chelating vs. Clarifying Products

As you peruse through hard water shampoos, the first thing DeBolt suggests is distinguishing whether a chelating shampoo (like the Living Proof Triple Detox Shampoo) or a clarifying shampoo (like Oribe's The Cleanse Clarifying Shampoo) would be best for your specific hair needs. As we mentioned above, both are effective in treating the effects of hard water, but they work in different ways.

“Chelating products are designed specifically to remove minerals,” he says. These work by actually attaching to the mineral buildup in the hair and washing it away. On the other hand, he says that clarifying shampoos often contain stronger detergents which make them great for breaking down all residue, including excess oil and product buildup in addition to mineral residue. However, clarifying shampoos can also be quite stripping and potentially fade color-treated hair.

Mineral-Targeting Ingredients

Regardless of the type of shampoo you choose, DeBolt says that it must claim to target mineral build-up, specifically copper, iron, and calcium. He considers vitamin C (like in the Briogeo Superfoods Mango + Cherry Oil Control & Balancing Shampoo) to be the most effective mineral-removing ingredient, but another great ingredient to keep an eye out for is apple cider vinegar (which can be found in the dphue Apple Cider Vinegar Hair Rinse) .

A Gentle Formula

DeBolt stresses that the formula you choose should be gentle. Even as you remove minerals and buildup from your hair and scalp, you don’t want to strip them of their natural oils entirely. This can lead to increased sebum production and result in an oily scalp.

FAQ
  • How often should you use shampoo for hard water?

    According to DeBolt, you should be using shampoos for hard water as often as you shampoo, or at least every other wash, for them to be effective. If clarifying and chelating shampoos are too stripping for your hair, be sure to follow up with a conditioner or other moisturizing treatment.

  • How can you protect hair from hard water?

    There are a number of things you can do to prevent hard water from damaging your hair, from installing a water softener and replacing your shower head to trying a new shampoo and conditioner. If you're taking the latter route, any chelating or clarifying shampoo will do the trick to remove build-up from product, pollution and hard water.

Why Trust Byrdie

Byrdie contributor Melanie Rud has over a decade of experience in the beauty industry, writing for some of the biggest magazines and websites out there. She does have hard water in her apartment, so she both installed a shower filter and tries to use one of these clarifying shampoo formulas once every two weeks or so.

Updated by Caitlyn Martyn
Article Sources
Byrdie takes every opportunity to use high-quality sources, including peer-reviewed studies, to support the facts within our articles. Read our editorial guidelines to learn more about how we keep our content accurate, reliable and trustworthy.
  1. Luqman M, Ramzan M, Javaid U, Ali R, Shoaib M, Luqman M. To evaluate and compare changes in baseline strength of hairs after treating them with deionized water and hard water and its role in hair breakageInt J Trichol. 2018;10(3):113. doi: 10.4103/ijt.ijt_115_16

  2. Gavazzoni Dias MF, de Almeida AM, Cecato PM, Adriano AR, Pichler J. The Shampoo pH can Affect the Hair: Myth or Reality?Int J Trichology. 2014;6(3):95-99. doi:10.4103/0974-7753.139078

  3. Chelating Agents. In: LiverTox: Clinical and Research Information on Drug-Induced Liver Injury. Bethesda (MD): National Institute of Diabetes and Digestive and Kidney Diseases; January 23, 2017.

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